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Crystal structure of a methimazole-based ionic liquid

Title: Crystal structure of a methimazole-based ionic liquid.
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Name(s): Gaitor, Jamie C., author
Zayas, Manuel Sanchez, author
Myrthil, Darrel J., author
White, Frankie, author
Hendrich, Jeffrey M., author
Sykora, Richard E., author
O'Brien, Richard A., author
Reilly, John T., author
Mirjafari, Arsalan, author
Type of Resource: text
Genre: Article
Date Issued: 2015-12-01
Language(s): English
Abstract: The structure of 1-methyl-2-(prop-2-en-1-ylsulfanyl)-1H- imidazol-3-ium bromide, C7H11N2S+􏰀Br􏰁, has monoclinic (P21/c) symmetry. In the crystal, the components are linked by N—H􏰀􏰀􏰀Br and C—H􏰀􏰀􏰀Br hydrogen bonds. The crystal structure of the title compound undeniably proves that methimazole reacts through the thione tautomer, rather than the thiol tautomer in this system.
Identifier: 10.1107/S2056989015022136 (doi), fgcu_ir_000082 (IID), http://scripts.iucr.org/cgi-bin/paper?S2056989015022136 (uri)
Subject(s): crystal structure
ionic liquids
methimazole
S-allylation
nitrogen heterocycle
Persistent Link to This Record: http://purl.flvc.org/fgcu/flvc_fgcu_islandoraimporter_10.1107_S2056989015022136_1521569516
Use and Reproduction: publisher
Owner Institution: FGCU
Is Part Of: Acta Crystallographica Section E Crystallographic Communications.
2056-9890